ENVIRON SCI TECHNOL:研究人员称玩具是婴幼儿接触危险元素的来源

2018-01-27 海北 MedSci原创

在过去的几十年里,越来越多的证据表明重金属和类金属在相对较低剂量存在急性和慢性毒性,导致消费品中许多重金属和类金属的使用受到越来越多的限制。但是,婴儿可能暴露于更大量的金属和类金属,因为他们倾向于利用口腔探索玩具的味道,质地和形状。

在过去的几十年里,越来越多的证据表明重金属和类金属在相对较低剂量存在急性和慢性毒性,导致消费品中许多重金属和类金属的使用受到越来越多的限制。但是,婴儿可能暴露于更大量的金属和类金属,因为他们倾向于利用口腔探索玩具的味道,质地和形状。

近日,来自英国普利茅斯大学的研究人员通过X射线荧光光谱法对英国200多种二手塑料玩具进行了有害元素(砷,钡,镉,铬,汞,铅,锑,硒)和溴的分析,溴是作为溴系阻燃剂的代用品。

除砷,汞和硒外,每种元素都在> 20种玩具或其组分中检测到,其中溴,镉和铅的含量最高,最高浓度分别约为16,00020,0005000μgg-1。这个含量从潜在的暴露角度来看十分令人关注。

在模拟的胃部条件(0.07M HCl)下,研究人员对26个玩具的成分迁移进行评估,随后通过电感耦合等离子体光谱法进行分析。在8个案例中,镉和铅含量超出了目前欧盟玩具安全指令(分别为1723μg-1)规定的迁移限制,镉从黄色和红色乐高积木中释放的量甚至超过其限制一个数量级。

另外两个案例可能含有不符合规定的可迁移铬,其中一个案例也含有> 250μgg-1可迁移溴。

虽然对二手玩具没有追溯性规定,但消费者应该注意,旧的,可入口的塑料物品可能会成为婴幼儿接触危险元素的来源。


原始出处:

Andrew Turner et al. Concentrations and migratabilities of hazardous elements in second-hand children’s plastic toysEnvironmental Science & Technology, 2018; DOI: 10.1021/acs.est.7b04685


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    2018-09-11 shock_melon
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    2018-01-29 july_979
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    2018-01-27 龙胆草

    学习谢谢分享

    0

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    2018-01-27 明月清辉

    谢谢分享.学习了

    0

  6. [GetPortalCommentsPageByObjectIdResponse(id=1907544, encodeId=7c91190e54451, content=<a href='/topic/show?id=379fe3364c9' target=_blank style='color:#2F92EE;'>#研究人员#</a>, beContent=null, objectType=article, channel=null, level=null, likeNumber=32, replyNumber=0, topicName=null, topicId=null, topicList=[TopicDto(id=73364, encryptionId=379fe3364c9, topicName=研究人员)], attachment=null, authenticateStatus=null, createdAvatar=, createdBy=db5b227, createdName=gostraight, createdTime=Sat Feb 17 14:11:00 CST 2018, time=2018-02-17, status=1, ipAttribution=), GetPortalCommentsPageByObjectIdResponse(id=1652241, encodeId=28c8165224166, content=<a href='/topic/show?id=13d01e24509' target=_blank style='color:#2F92EE;'>#TEC#</a>, beContent=null, objectType=article, channel=null, level=null, likeNumber=23, replyNumber=0, topicName=null, topicId=null, topicList=[TopicDto(id=17245, encryptionId=13d01e24509, topicName=TEC)], attachment=null, authenticateStatus=null, createdAvatar=null, createdBy=852f24292001, createdName=shock_melon, createdTime=Tue Sep 11 21:11:00 CST 2018, time=2018-09-11, status=1, ipAttribution=), GetPortalCommentsPageByObjectIdResponse(id=1524256, encodeId=bb101524256b4, content=<a href='/topic/show?id=053710045ad' target=_blank style='color:#2F92EE;'>#iron#</a>, beContent=null, objectType=article, channel=null, level=null, likeNumber=31, replyNumber=0, topicName=null, topicId=null, topicList=[TopicDto(id=10045, encryptionId=053710045ad, topicName=iron)], attachment=null, authenticateStatus=null, createdAvatar=null, createdBy=3f1b11597510, createdName=july_979, createdTime=Mon Jan 29 00:11:00 CST 2018, time=2018-01-29, status=1, ipAttribution=), GetPortalCommentsPageByObjectIdResponse(id=282496, encodeId=123c282496f8, content=学习谢谢分享, beContent=null, objectType=article, channel=null, level=null, likeNumber=69, replyNumber=0, topicName=null, topicId=null, topicList=[], attachment=null, authenticateStatus=null, createdAvatar=https://wx.qlogo.cn/mmopen/mStl88fu4Nd44v3xHnnictn9UpctwtH62EPQ59TMdI9lnqHMgQ16nH7GmGCfpzicsHgjibYVk6vwSpXrC86gMibRkoaIzf5HwSz7/0, createdBy=78cc1691107, createdName=龙胆草, createdTime=Sat Jan 27 09:50:54 CST 2018, time=2018-01-27, status=1, ipAttribution=), GetPortalCommentsPageByObjectIdResponse(id=282487, encodeId=9bd228248e5b, content=谢谢分享.学习了, beContent=null, objectType=article, channel=null, level=null, likeNumber=63, replyNumber=0, topicName=null, topicId=null, topicList=[], attachment=null, authenticateStatus=null, createdAvatar=https://wx.qlogo.cn/mmopen/NUyjXTCJjo6Nx0VGA4QMDzOP8oAgnV4h51EjSfehJ9QxyiaSmw8PB56BhY8KXFSxHCibXrzcy4abrzSibXQPxJ9kzrLcJyhhB8a/0, createdBy=1d3b1672603, createdName=明月清辉, createdTime=Sat Jan 27 09:29:44 CST 2018, time=2018-01-27, status=1, ipAttribution=), GetPortalCommentsPageByObjectIdResponse(id=282480, encodeId=19722824801f, content=很好的文章.谢谢分享, beContent=null, objectType=article, channel=null, level=null, likeNumber=61, replyNumber=0, topicName=null, topicId=null, topicList=[], attachment=null, authenticateStatus=null, createdAvatar=https://wx.qlogo.cn/mmopen/Q3auHgzwzM4o2XVpJ6449yqDsjibydI5HnJ8MibGxNn4HZiaZib0bdfibbwoz3KQrIyN9AGxq36ZlZRNicYlPfOOWMtwgsajY6mGNFiaPclFdowjD0/0, createdBy=97bd1338592, createdName=清风拂面, createdTime=Sat Jan 27 09:26:05 CST 2018, time=2018-01-27, status=1, ipAttribution=)]
    2018-01-27 清风拂面

    很好的文章.谢谢分享

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