Evaluating f-Orbital Participation in the UV=E Multiple Bonds of [U(E)(NR2)3] (E = O, NSiMe3, NAd; R=SiMe3)

Nguyen, TH; Paul, EL; Lukens, WW; Hayton, TW

Hayton, TW (通讯作者)，Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA.;Lukens, WW (通讯作者)，Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA.

INORGANIC CHEMISTRY, 2023; 62 (16): 6447

Abstract

The reaction of 1 equiv of 1-azidoadamantane with [UIII(NR2)3] (R = SiMe3) in Et2O results in the formation of [UV(NR2)3(NAd)] (1, Ad = 1-adamantyl) i......

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