Direct Nucleophilic Substitution Reaction of Cage B-H Bonds by Grignard Reagents: A Route to Regioselective B4-Alkylation of o-Carboranes

Tang, C; Zhang, JJ; Xie, ZW

Xie, ZW (reprint author), Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China.; Xie, ZW (reprint author), Chinese Univ Hong Kong, State Key Lab Synthet Chem, Shatin, Hong Kong, Peoples R China.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017; 56 (30): 8642

Abstract

Direct nucleophilic substitution reaction of cage B-H bonds of o-carboranes by Grignard reagents in the absence of any transition metals has been achi......

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