Ir(III)/Ir(V) or Ir(I)/Ir(III) Catalytic Cycle? Steric-Effect-Controlled Mechanism for the para-C-H Borylation of Arenes

Zhu, L; Qi, XT; Li, YZ; Duan, M; Zou, LF; Bai, RP; Lan, Y

Bai, RP; Lan, Y (reprint author), Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China.

ORGANOMETALLICS, 2017; 36 (11): 2107

Abstract

Density functional theory method N12 was used to study the mechanism of the [Ir(cod)OH](2)/Xyl-MeO-BIPHEP-catalyzed para-selective C-H borylation reac......

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