Synthesis, PtS-type structure, and anomalous mechanics of the Cd(CN)(2) precursor Cd(NH3)(2)[Cd(CN)(4)]

Coates, CS; Makepeace, JW; Seel, AG; Baise, M; Slater, B; Goodwin, AL

Goodwin, AL (reprint author), Univ Oxford, Dept Chem, Inorgan Chem Lab, S Parks Rd, Oxford OX1 3QR, England.

DALTON TRANSACTIONS, 2018; 47 (21): 7263

Abstract

We report the nonaqueous synthesis of Cd(CN)(2) by oxidation of cadmium metal with Hg(CN)(2) in liquid ammonia. The reaction proceeds via an intermedi......

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