Transient Phosphenium and Arsenium Ions versus Stable Stibenium and Bismuthenium Ions

Olaru, M; Duvinage, D; Lork, E; Mebs, S; Beckmann, J

Beckmann, J (reprint author), Univ Bremen, Inst Anorgan Chem & Kristallog, Leobener Str 7, D-28359 Bremen, Germany.; Mebs, S (reprint author), Free Univ Berlin, Inst Expt Phys, Arnimallee 14, D-14195 Berlin, Germany.

CHEMISTRY-A EUROPEAN JOURNAL, 2019; 25 (65): 14758

Abstract

Fluoride abstraction from bis-m-terphenylelement fluorides (2,6-Mes(2)C(6)H(3))(2)EF (E=P, As) generated the highly reactive phosphenium ion [(2,6-Mes......

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