Formation of Gold(III) Alkyls from Gold Alkoxide Complexes

Chambrier, I; Rosca, DA; Fernandez-Cestau, J; Hughes, DL; Budzelaar, PHM; Bochmann, M

Bochmann, M (reprint author), Univ East Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England.; Budzelaar, PHM (reprint author), Univ Manitoba, Dept Chem, Winnipeg, MB R3T 2N2, Canada.; Budzelaar, PHM (reprint author), Univ Naples Federico II, Dept Chem Sci

ORGANOMETALLICS, 2017; 36 (7): 1358

Abstract

The gold(III) methoxide complex (C<^>N<^>C)AuOMe (1) reacts with tris(p-tolyl)phosphine in benzene at room temperature under O abstraction......

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