Activation of H-2 and Et3SiH by the Borinium Cation [Mes(2)B](+): Avenues to Cations [MesB(mu-H)(2)(mu-Mes)BMes](+) and [H2B(mu-H)(mu-Mes)B(mu-Mes)(mu-H)BH2](+)

Bamford, KL; Qu, ZW; Stephan, DW

Stephan, DW (reprint author), Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada.; Qu, ZW (reprint author), Univ Bonn, Mulliken Ctr Theoret Chem, Beringstr 4, D-53115 Bonn, Germany.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019; 141 (15): 6180

Abstract

Reaction of dihydrogen and the borinium cation salt [Mes(2)B][B(C6F5)(4)] gave an arene-stabilized mesityl-borenium cation, which isotopically scrambl......

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