Thermodynamics of H+/H-center dot/H-/e(-) Transfer from [CpV(CO)(3)H](-): Comparisons to the Isoelectronic CpCr(CO)(3)H

Kuo, JL; Gunasekara, T; Hansen, A; Vibbert, HB; Bohle, F; Norton, JR; Grimme, S; Quinlivan, PJ

Norton, JR (reprint author), Columbia Univ, Dept Chem, 3000 Broadway, New York, NY 10027 USA.; Grimme, S (reprint author), Rheinische Friedrich Wilhelms Univ Bonn, Mulliken Ctr Theoret Chem, Inst Phys & Theoret Chem, Beringstr 4, D-53115 Bonn, Germany.

ORGANOMETALLICS, 2019; 38 (21): 4319

Abstract

Hydrogen atom (H-center dot) donors generated from H-2 facilitate the atom efficient reduction of small molecule substrates. However, generating H-cen......

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