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Construction of Diverse Polycyclic Structures via Group 9 Metal - Catalyzed Cycloisomerization of 1,6-Diyne Derivatives

期刊: JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023; 81 (2)

Polycyclic structures are found in many natural products and pharmaceuticals. The transition-metal-catalyzed cycloisomerization of unsaturated compoun......

Cationic Iodine( I)-Mediated Electrophilic Cyclization of Alkynes

期刊: JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023; 81 (8)

Cationic iodine(I) - mediated electrophilic cyclization, termed iodocyclization, allows ring formation and iodination at the same time. In particular,......

Hydride Shift Mediated C(sp3)-H Bond Functionalization(Internal Redox Reaction)

期刊: JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023; 81 (6)

Direct transformation of unactivated bond such as C-H bond is an important transformation. Because of its high utility from the viewpoints of atom eco......

Total Syntheses of the Herqulines

期刊: JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023; 81 (1)

Herqulines are small alkaloids with highly distorted structures that are synthesized from two tyrosine molecules. Between December 2018 and January 20......

Pseudo-Glycoconjugates: Synthesis and Biological Function of C-Glycoside Analogues of Glycoconjugates

期刊: JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023; 81 (7)

The authors have been working on the development of pseudo-glycans (pseudo-glycoconjugates) in which the O-glycosidic linkage of the natural-type glyc......

Divergent Transformation of Carboxylic Acids through Photocatalytic Decarboxylation with Hypervalent Iodine Reagents

期刊: JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023; 81 (11)

Carboxylic acids are one of the most important functional groups found in various feedstocks. Their significance lies in their pivotal role as key int......

Development of Novel Methodologies for Functionalization of Isoxazoles

期刊: JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023; 81 (3)

Isoxazole is a five-membered heteroaromatic ring that is a highly important framework with widespread applications in pharmaceuticals and agrochemical......

Dual Functionalization of Organic Compounds via Oxidation of Halogen

期刊: JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023; 81 (10)

Dual functionalization in organic synthesis is an elegant and powerful method for simultaneously introducing two different functional groups regio - s......

Linearly-connected Tetrafluoro-λ6- sulfanyl Molecules: Synthesis and Challenges

期刊: JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023; 81 (5)

Isosterism and bioisosterism are concepts in molecular design of specialty materials and drugs compounds. Fluorine and fluorine-containing functional ......

Development of Novel Hypervalent Iodine Compounds Bearing Intramolecular Halogen Bonding

期刊: JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023; 81 (5)

In recent years, halogen bonding(XB)interaction has attracted much attention in organic synthesis, especially for the activation of substrates. On the......

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