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Titanium-Mediated C-C Coupling of Imidoylstannanes for the Synthesis of Tetraaryl Diimines. Isolation of Titanium Iminoacyl and Ene-diamido Intermediates

期刊: ORGANOMETALLICS, 2023; 42 (1)

An efficient one-pot synthesis of tetraaryl alpha-diimines with various aryl groups via TiCl4-mediated C-C coupling of imidoylstannanes followed by di......

Mechanistic, Computational Study of Alkene-Diazene Heterofunctional Cross-Metathesis Catalyzed by Ruthenium Complexes

期刊: ORGANOMETALLICS, 2023; ()

Density functional theory calculations were used to study the cross-metathesis reaction between diazenes and alkenes catalyzed by 17 different rutheni......

Palladium-Catalyzed Hydrophosphination of Terminal Alkynes with Diphenylphosphine Oxide in the Presence of Tetraphenyldiphosphine Monoxide

期刊: ORGANOMETALLICS, 2023; 42 (18)

In this study, the Pd(OAc)2-catalyzed hydrophosphination of terminal alkynes was investigated in detail by using various diphosphines, which have a P-......

Iron-Aryloxide Complex Bearing Bis(dipyrromethene) Ligands for the Ring-Opening Polymerization of ?-Caprolactone

期刊: ORGANOMETALLICS, 2023; 42 (7)

We report a high-spin iron system supported by two dipyrromethene ligands for ring-opening polymerization of epsilon-caprolactone. The four-coordinati......

Ethylene Tri-/Tetramerization Catalysts Supported by Phenylene- Bridged Mixed Alkyl/Aryl Diphosphine Ligands

期刊: ORGANOMETALLICS, 2023; 42 (8)

Cr(III) complexes supported by phenylene-bridged diphosphine ligands with P-alkyl substitution were prepared and evaluated in ethylene tri-/tetrameriz......

A Bifunctional Ruthenium Catalyst for Effective Renewable Hydrogen Production from Biomass-Derived Sorbitol

期刊: ORGANOMETALLICS, 2023; 42 (9)

In the present worldwide situation, the transition to a more sustainable hydrogen economy from the prevailing energy infrastructure is gaining great a......

Synthesis and Characterization of Cobalt(II/II) and Cobalt(II/III) Macrocyclic Complexes and Their Application in the Copolymerization of Epoxides and CO2

期刊: ORGANOMETALLICS, 2023; 42 (13)

The synthesis and characterization of six dinuclear cobaltcomplexesbearing a conjugated macrocyclic ligand are reported. The condensationof 2,6-diform......

Cyclometalated Platinum(II) Complexes with 10-(Aryl)phenoxarsine Ligands: Synthesis, Structure, and Photophysical Properties

期刊: ORGANOMETALLICS, 2023; 42 (18)

A series of C boolean AND N-cyclometalated platinum(II) complexes[Pt(ppy)X(L)] (ppy = 2-phenylpyridinate, X = Cl and I)with 10-(aryl)phenoxarsines,nam......

Electrogenerated Sm(II)-Catalyzed Carbon Dioxide Reduction for β-Hydrocarboxylation of Styrenes

期刊: ORGANOMETALLICS, 2023; 42 (12)

The synthesis of carboxylic acids from low-value materialssuchas alkenes using CO2 as a C-1-building blockremains a real challenge for synthetic chemi......

Competitive Double Friedel-Crafts 2,5-and 1′,2-Diacylation of Monophosphaferrocenes

期刊: ORGANOMETALLICS, 2023; 42 (13)

Thedouble Friedel-Crafts acylation of 2,5-dihydro-1-phosphaferrocenes 1 was established by the stepwise introduction of two acylgroups and conduction ......

Recent Advances in Photomechanical Crystals Made from Metal-Organic and Organometallic Complexes

期刊: ORGANOMETALLICS, 2023; 42 (16)

Photomechanical crystals that can directly convert lightenergyinto mechanical work attracted increasing attention due to their dramaticbehaviors and p......

Three-Coordinate Halide and Methyl Complexes of Chromium, Manganese, Iron, Cobalt, and Nickel Enabled by an Imidazolin-2-iminato Ligand

期刊: ORGANOMETALLICS, 2023; 42 (17)

Accessing low-coordinate halide and methyl complexes requires a bulky monodentate or bidentate ligand. Here, the synthesis and characterization of thr......

Synthesis, Structure, and Reactivity of Rare-Earth Metal Carboryne Complexes

期刊: ORGANOMETALLICS, 2023; 42 (7)

Rare-earth metal carboryne complexes LRE-(C2B10H10)(thf)n [n = 2, RE = Y (1a), Er (1b); n = 1, RE = Y (2); L = 2-(2,5-Me2C4H2N)C6H4NC(Ph)N(2,6-iPr2C6H......

Imidazolin-2-imine and Imidazolin-2-methylidene Substitutions to Benzene, Pyridine, Phosphine, and N-Heterocyclic Carbene Predict Highly Electron-rich Ligands

期刊: ORGANOMETALLICS, 2023; 42 (7)

Majority of the substituents in organic and organometallic chemistry are electron-withdrawing in nature toward substrates/ligands. Even for the most e......

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