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Strategies, Status, and Challenges in Wafer Scale Single Crystalline Two-Dimensional Materials Synthesis

期刊: CHEMICAL REVIEWS, 2021; 121 (11)

The successful exfoliation of graphene has given a tremendous boost to research on various two-dimensional (2D) materials in the last 15 years. Differ......

Oxidation-Induced "One-Pot" Click Chemistry

期刊: CHEMICAL REVIEWS, 2021; 121 (12)

Click chemistry has been established rapidly as one of the most valuable methods for the chemical transformation of complex molecules. Due to the rapi......

Catalytic Enantioselective Alkylation of Prochiral Enolates

期刊: CHEMICAL REVIEWS, 2021; 121 (15)

The asymmetric alkylation of enolates is a particularly versatile method for the construction of a-stereogenic carbonyl motifs, which are ubiquitous i......

Magnetically Driven Micro and Nanorobots

期刊: CHEMICAL REVIEWS, 2021; 121 (8)

Manipulation and navigation of micro and nanoswimmers in different fluid environments can be achieved by chemicals, external fields, or even motile ce......

Chemical Aspects of Human and Environmental Overload with Fluorine

期刊: CHEMICAL REVIEWS, 2021; 121 (8)

Over the last 100-120 years, due to the ever-increasing importance of fluorine-containing compounds in modern technology and daily life, the explosive......

Gold-Catalyzed Conversion of Highly Strained Compounds

期刊: CHEMICAL REVIEWS, 2021; 121 (14)

The past decade has witnessed the golden age of homogeneous gold-catalyzed reactions, especially those that involve the transformation of highly strai......

New Strategies for the Synthesis of Aliphatic Azides

期刊: CHEMICAL REVIEWS, 2021; 121 (7)

Aliphatic azides are a versatile class of compounds found in a variety of biologically active pharmaceuticals. These compounds are also recognized as ......

1,2-Migrations onto Gold Carbene Centers

期刊: CHEMICAL REVIEWS, 2021; 121 (14)

Gold carbenes are highly active intermediates in homogeneous gold catalysis, enabling a large array of transformations such as C-H/X-H insertions, cyc......

Nonaqueous Rechargeable Aluminum Batteries: Progresses, Challenges, and Perspectives

期刊: CHEMICAL REVIEWS, 2021; 121 (8)

For significantly increasing the energy densities to satisfy the growing demands, new battery materials and electrochemical chemistry beyond conventio......

High-Throughput Methods in the Discovery and Study of Biomaterials and Materiobiology

期刊: CHEMICAL REVIEWS, 2021; 121 (8)

The complex interaction of cells with biomaterials (i.e., materiobiology) plays an increasingly pivotal role in the development of novel implants, bio......

Recent Development of Aryl Diazonium Chemistry for the Derivatization of Aromatic Compounds

期刊: CHEMICAL REVIEWS, 2021; 121 (10)

Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-increasing importance of aryl diazonium salts spanning m......

Microfluidics for Drug Development: From Synthesis to Evaluation

期刊: CHEMICAL REVIEWS, 2021; 121 (13)

Drug development is a long process whose main content includes drug synthesis, drug delivery, and drug evaluation. Compared with conventional drug dev......

Recent Advances in Catalytic Asymmetric Construction of Atropisomers

期刊: CHEMICAL REVIEWS, 2021; 121 (8)

Atropisomerism is a stereochemical behavior portrayed by three-dimensional molecules that bear rotationally restricted sigma bond. Akin to the well-re......

Nitrene Transfer and Carbene Transfer in Gold Catalysis

期刊: CHEMICAL REVIEWS, 2021; 121 (14)

Catalytic transformations involving metal carbenes are considered one of the most important aspects of homogeneous transition metal catalysis. Recentl......

Light in Gold Catalysis

期刊: CHEMICAL REVIEWS, 2021; 121 (14)

Within the wide family of gold-catalyzed reactions, gold photocatalysis intrinsically features unique elementary steps. When gold catalysis meets phot......

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