Exploring New Zintl Phases in the 9-4-9 Family via Al Substitution. Synthesis, Structure, and Physical Properties of Ae(9)Mn(4-x)Al(x)Sb(9) (Ae = Ca, Yb, Eu)

Liu, XC; Liu, KF; Wang, QQ; Wang, YM; Pan, MY; Xia, SQ

Liu, XC (corresponding author), Shandong Jiaotong Univ, Sch Civil Engn, Jinan 250023, Shandong, Peoples R China.; Xia, SQ (corresponding author), Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Shandong, Peoples R China.

INORGANIC CHEMISTRY, 2020; 59 (6): 3709

Abstract

Three new quaternary Zintl phases with the "9-4-9" formula, Ae(9)Mn(4-x)Al(x)Sb(9) (Ae = Ca, Yb, Eu), have been synthesized using Pb as the metal flux......

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