Isotope Probing of the UDP-Apiose/UDP-Xylose Synthase Reaction: Evidence of a Mechanism via a Coupled Oxidation and Aldol Cleavage

Eixelsberger, T; Horvat, D; Gutmann, A; Weber, H; Nidetzky, B

Nidetzky, B (reprint author), Graz Univ Technol, NAWI Graz, Inst Biotechnol & Biochem Engn, Petersgasse 12, A-8010 Graz, Austria.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017; 56 (9): 2503

Abstract

The C-branched sugar D-apiose (Api) is essential for plant cell-wall development. An enzyme-catalyzed decarboxylation/pyranoside ring-contraction reac......

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