Evidence for a Di-mu-oxo Diamond Core in the Mn(IV)/Fe(IV) Activation Intermediate of Ribonucleotide Reductase from Chlamydia trachomatis

Martinie, RJ; Blaesi, EJ; Krebs, C; Bollinger, JM; Silakov, A; Pollock, CJ

Silakov, A; Pollock, CJ (reprint author), Penn State Univ, Dept Chem, University Pk, PA 16802 USA.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017; 139 (5): 1950

Abstract

High-valent iron and manganese complexes effect some of the most challenging biochemical reactions known, including hydrocarbon and water oxidations a......

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