Reactions of B-2(o-tolyl)(4) with Boranes: Assembly of the Pentaborane(9), HB[B(o-tolyl)(mu-H)](4)

Bamford, KL; Qu, ZW; Stephan, DW

Stephan, DW (corresponding author), Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S3H6, Canada.; Qu, ZW (corresponding author), Rhein Friedrich Wilhelms Univ Bonn, Mulliken Ctr Theoret Chem, Inst Phys & Theoret Chem, Beringstr 4, D-53115 Bonn, Germany.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021; 60 (15): 8532

Abstract

Reactions of the diborane(4) B-2(o-tolyl)(4) and monohydridoboranes are shown to give B(o-tolyl)(3) and (o-tolyl)BR2 (R-2=(C8H14) 3, cat 4, pin 5, (C6......

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