Mononuclear gallium complexes with the redox-active dmp-bian ligand (dmp-bian is 1,2-bis[(2,6-dimethylphenyl)imino]acenaphthene): synthesis and reactions with alkynes

Skatova, AA; Bazyakina, NL; Fedushkin, IL; Piskunov, AV; Druzhkov, NO; Cherkasov, AV

Skatova, AA (reprint author), Russian Acad Sci, GA Razuvaev Inst Organometall Chem, 49 Ul Tropinina, Nizhnii Novgorod 603137, Russia.

RUSSIAN CHEMICAL BULLETIN, 2019; 68 (2): 275

Abstract

The direct reduction of 1,2-bis[(2,6-dimethylphenyl)imino]acenaphthene (dmp-bian (1)) with gallium metal in toluene affords the solvent-free bis-ligan......

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