Synthesis of [Pt-12(CO)(20)(dppm)(2)](2-) and [Pt-18(CO)(30)(dPPm)(3)](2-) Heteroleptic Chini-type Platinum Clusters by the Oxidative Oligomerization of [Pt-6(CO)(12)(dPpm)](2-)

Berti, B; Cesari, C; Conte, F; Ciabatti, I; Femoni, C; Iapalucci, MC; Vacca, F; Zacchini, S

Zacchini, S (reprint author), Univ Bologna, Dipartimento Chim Ind Toso Montanari, Viale Risorgimento 4, I-40136 Bologna, Italy.

INORGANIC CHEMISTRY, 2018; 57 (13): 7578

Abstract

The reactions of [Pt-6(CO)(12)](2-) with CH(PPh2)(2) (dppm), CH2=C(PPh2)(2) (P<^>P), and Fe(C5H4PPh2)(2) (dppf) proceed via nonredox substitutio......

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