Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron

Braunschweig, H; Krummenacher, I; Legare, MA; Matler, A; Radacki, K; Ye, Q

Braunschweig, H (reprint author), Julius Maximilians Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany.; Braunschweig, H (reprint author), Julius Maximilians Univ Wurzburg, Inst Sustainable Chem & Catalysis Boron, D-97074 Wurzburg, Germany.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017; 139 (5): 1802

Abstract

The carbon monoxide adduct of an unhindered and highly reactive CAAC-bound arylborylene, [(CAAC)B(CO)Ar] (CAAC = cyclic (alkyl) (amino)carbene), has b......

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