LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25:Topochemically Reduced, Mixed Valence Rh(I)/Rh(III) Oxides

Xu, ZY; Palgrave, RG; Hayward, MA

Hayward, MA (corresponding author), Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England.

INORGANIC CHEMISTRY, 2020; 59 (18): 13767

Abstract

Topochemical reduction of the n = 1 RuddlesdenPopper phases LaSrCo(0.5)Rh0.5O4 and LaSrNi0.5Rh0.5O4 with Zr yields LaSrCo0.5Rh0.5O3.25 and LaSrN(i0.)5......

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