Gold(I)-Mediated Cycloisomerization/Cycloaddition Enables Bioinspired Syntheses of Neonectrolides B-E and Analogues

Purgett, TJ; Dyer, MW; Bickel, B; McNeely, J; Porco, JA

Porco, JA (reprint author), Boston Univ, CMD, Dept Chem, 590 Commonwealth Ave, Boston, MA 02215 USA.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019; 141 (38): 15135

Abstract

Development of a synthetic route to the oxaphenalenone (OP) natural products neonectrolides B-E is described. The synthesis relies on gold-catalyzed 6......

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