High-Valent d(7) Ni-III versus d(8) Cu-III Oxidants in PCET

Unjaroen, D; Gericke, R; Lovisari, M; Neils, D; Mondal, P; Pirovano, P; Twamley, B; Farquhar, ER; McDonald, AR

McDonald, AR (reprint author), Univ Dublin, Trinity Coll Dublin, Sch Chem, Dublin 2, Ireland.

INORGANIC CHEMISTRY, 2019; 58 (24): 16838

Abstract

Oxygenases have been postulated to utilize d(4) Fe-IV and d(8) Cu-III oxidants in proton-coupled electron transfer (PCET) hydrocarbon oxidation. In or......

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