Dissociative and Associative Concerted Mechanism for Ammonia Synthesis over Co-Based Catalyst

Ye, TN; Park, SW; Lu, YF; Li, J; Wu, JZ; Sasase, M; Kitano, M; Hosono, H

Ye, TN; Kitano, M; Hosono, H (corresponding author), Tokyo Inst Technol, Mat Res Ctr Element Strategy, Yokohama, Kanagawa 2268503, Japan.; Hosono, H (corresponding author), Natl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, Tsukuba, Ibaraki 3050044, Japan.; Ye, TN (corresponding author), Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Frontiers Sci Ctr Transformat Mol, Shanghai 200240, Peoples R China.; Kitano, M (corresponding author), Japan Sci & Technol Agcy JST, Precursory Res Embr

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021; 143 (32): 12857

Abstract

The current catalytic reaction mechanism for ammonia synthesis relies on either dissociative or associative routes, in which adsorbed N-2 dissociates ......

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