Anomalous Stoichiometry and Antiferromagnetic Ordering for the Extended Hydroxymanganese(II) Cubes/Hexacyanometalate-Based 3D-Structured [Mn-4(II)(OH)(4)][Mn-II(CN)(6)](OH2)(6)center dot H2O

Lapidus, SH; Stephens, PW; Kareis, CM; VanNatta, PE; Miller, JS

Stephens, PW (reprint author), SUNY Stony Brook, Dept Phys & Astron, Stony Brook, NY 11794 USA.; Miller, JS (reprint author), Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA.

CHEMISTRY-A EUROPEAN JOURNAL, 2019; 25 (7): 1752

Abstract

The reaction of Mn-II(O2CMe)(2) and NaCN or LiCN in water forms a light green insoluble material. Structural solution and Rietveld refinement of high-......

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