Synthesis of 6-Amino- and 6-Arylazoazulenes via Nucleophilic Aromatic Substitution and Their Reactivity and Properties

Shoji, T; Sugiyama, S; Takeuchi, M; Ohta, A; Sekiguchi, R; Ito, S; Yatsu, T; Okujima, T; Yasunami, M

Shoji, T (reprint author), Shinshu Univ, Grad Sch Sci & Technol, Matsumoto, Nagano 3908621, Japan.

JOURNAL OF ORGANIC CHEMISTRY, 2019; 84 (3): 1257

Abstract

The nucleophilic aromatic substitution (SNAr) reaction of diethyl 6-bromoazulene-1,3-dicarboxylate (1) with a variety of amines afforded the correspon......

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