Significant geometry and charge difference between the E-5(4-) bare clusters of group 14 Zintl anions and their coordinated form in [E-5{M(CO)(3)}(2)](4-) (E = Si, Ge, Sn, Pb; M = Cr, Mo, W) complexes-MedSci.cn

Significant geometry and charge difference between the E-5(4-) bare clusters of group 14 Zintl anions and their coordinated form in [E-5{M(CO)(3)}(2)](4-) (E = Si, Ge, Sn, Pb; M = Cr, Mo, W) complexes

Gholiee, Y; Salehzadeh, S; Khodaveisi, S

Gholiee, Y (reprint author), Malayer Univ, Fac Sci, Dept Chem, Malayer, Iran.; Salehzadeh, S (reprint author), Bu Ali Sina Univ, Fac Chem, Hamadan, Iran.

NEW JOURNAL OF CHEMISTRY, 2019; 43 (20): 7797

Abstract

In this paper, at first, the possible structures for E-5(n) Zintl ions (E = Si, Ge, Sn, Pb; n = 0, 2-, 4-) were investigated at the BP86/def2-TZVPP an......

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