Stabilisation of [(WF4)-F-V](+) by N- and P-Donor Ligands: Second-Order Jahn-Teller Effects in Octacoordinate d(1) Complexes

Turnbull, D; Wetmore, SD; Gerken, M

Gerken, M (corresponding author), Univ Lethbridge, Canadian Ctr Res Adv Fluorine Technol, 4401 Univ Dr West, Lethbridge, AB T1K 3M4, Canada.; Gerken, M (corresponding author), Univ Lethbridge, Dept Chem & Biochem, 4401 Univ Dr West, Lethbridge, AB T1K 3M4, Canada.

CHEMISTRY-A EUROPEAN JOURNAL, 2021; 27 (44): 11335

Abstract

The first isolated examples of cationic fluoridotungsten(V) complexes are reported as octacoordinate [WF4(L)(4)](+) (L=C5H5N, P(CH3)(3)). The [WF4(NC5......

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