Early-Transition-Metal Complexes of Functionalized Nonagermanide Clusters: Synthesis and Characterization of [Cp-2(MeCN)Ti(eta(1)-Ge-9{Si(TMS)(3)}(3))] and K-3[Cp2Ti(eta(1)-Ge-9{Si(TMS)(3)}(2))(2)]

Geitner, FS; Klein, W; Storcheva, O; Tilley, TD; Fassler, TF

Fassler, TF (reprint author), Tech Univ Munich, Dept Chem, Lichtenbergstr 4, D-85747 Garching, Germany.

INORGANIC CHEMISTRY, 2019; 58 (19): 13293

Abstract

Anionic clusters with a homoatomic [Ge-9] core are species with Ge atoms in low oxidation states. In this study their reaction with early-transition-m......

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