Unprecedented pentanuclear mixed-valence Pt-(II)-Pt-(IV) complex anion in Q(2)[Pt5Cl20] salts (Q = TBA, PPN)

Dell'Amico, DB; Labella, L; Marchetti, F; Ramello, S; Samaritani, S

Samaritani, S (reprint author), Dipartimento Chim & Chim Ind, Via G Moruzzi 13, I-56124 Pisa, Italy.

INORGANIC CHEMISTRY COMMUNICATIONS, 2018; 95 (): 167

Abstract

Red crystals of [TBA](2)[Pt5Cl20] were obtained by reacting [TBA](2)[PtCl6] with an excess of AlCl3 at room temperature in CH2Cl2. The salt [PPN](2)[P......

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