Successive Charge Transitions of Unusually High-Valence Fe3.5+: Charge Disproportionation and Intermetallic Charge Transfer

Hosaka, Y; Romero, FD; Ichikawa, N; Saito, T; Shimakawa, Y

Shimakawa, Y (reprint author), Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017; 56 (15): 4243

Abstract

A perovskite-structure oxide containing unusually high-valence Fe3.5+ was obtained by high-pressure synthesis. Instability of the Fe3.5+ in Ca0.5Bi0.5......

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