Theoretical Evidence for the Relevance of n(S) -> sigma*(C-P), sigma(C-S) -> sigma*(C-P), and n(F) -> sigma*(C-X) (X = H, C, O, S) Stereoelectronic Interactions

Juaristi, E; Notario, R

Juaristi, E (reprint author), Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, 2508 Colonia Zacatenco, Ciudad De Mexico 07360, Mexico.; Juaristi, E (reprint author), El Colegio Nacl, Ctr Hist, Luis Gonzalez Obregon 23, Ciudad De Mexico 0602

STEREOCHEMISTRY AND GLOBAL CONNECTIVITY: THE LEGACY OF ERNEST L ELIEL, VOL 2, 2017; 1258 ( ): 3

Abstract

Three decades after the discovery of a strong S-C-Panomeric effect in 2-diphenylphosphinoy1-1,3-dithiane (1), a suitable interpretation was pendimi: n......

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