Redox active Ni-Pd carbonyl alloy nanoclusters: syntheses, molecular structures and electrochemistry of [Ni22-xPd20+x(CO)(48)](6-) (x=0.62), [Ni29-xPd6+x(CO)(42)](6-) (x=0.09) and [Ni29+xPd6-x(CO)(42)](6-) (x=0.27)

Berti, B; Cesari, C; Femoni, C; Funaioti, T; Lapalucci, MC; Zacchini, S

Zacchini, S (corresponding author), Univ Bologna, Dipartimento Chim Ind Toso Montanari, Viale Risorgimento 4, I-40136 Bologna, Italy.

DALTON TRANSACTIONS, 2020; 49 (17): 5513

Abstract

A redox active Ni-Pd alloy nanocluster [Ni22-xPd20+x(CO)(48)](6-) (x = 0.62) ([1](6-)) was obtained from the redox condensation of [NBu4](2)[Ni-6(CO)(......

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