Stepwise Reduction of Dinitrogen by a Uranium-Potassium Complex Yielding a U(VI)/U(IV) Tetranitride Cluster

Jori, N; Barluzzi, L; Douair, I; Maron, L; Fadaei-Tirani, F; Zivkovic, I; Mazzanti, M

Mazzanti, M (corresponding author), Ecole Polytech Fed Lausanne EPFL, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland.; Maron, L (corresponding author), Inst Natl Sci Appl, Lab Phys & Chim Nanoobjets, F-31077 Toulouse 4, France.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021; 143 (29): 11225

Abstract

Multimetallic cooperativity is believed to play a key role in the cleavage of dinitrogen to nitrides (N3-), but the mechanism remains ambiguous due to......

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