Chalcogen Impact on Covalency within Molecular [Cu-3(mu(3)-E)](3+) Clusters (E = O, S, Se): A Synthetic, Spectroscopic, and Computational Study

Cook, BJ; Di Francesco, GN; Ferreira, RB; Lukens, JT; Silberstein, KE; Keegan, BC; Catalano, VJ; Lancaster, KM; Shearer, J; Murray, LJ

Murray, LJ (reprint author), Univ Florida, Ctr Catalysis, Gainesville, FL 32611 USA.; Murray, LJ (reprint author), Univ Florida, Ctr Heterocycl Cpds, Dept Chem, Gainesville, FL 32611 USA.; Lancaster, KM (reprint author), Cornell Univ, Dept Chem & Chem Bio

INORGANIC CHEMISTRY, 2018; 57 (18): 11382

Abstract

Reaction of the tricopper(I)-dinitrogen tris(beta-diketiminate) cyclophane, Cu-3(N-2)L, with O-atom-transfer reagents or elemental Se affords the oxid......

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