Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn-10](3-), [Rh@Sn-12](3-), [Rh-2@Sn-17](6-) and the first triply-fused stannide, [Rh-3@Sn-24](5-)

Liu, C; Jin, X; Li, LJ; Xu, J; McGrady, JE; Sun, ZM

Sun, ZM (reprint author), Nankai Univ, Sch Mat Sci & Engn, Tianjin 300350, Peoples R China.; Sun, ZM (reprint author), Nankai Univ, Natl Inst Adv Mat, Tianjin Key Lab Rare Earth Mat & Applicat, Ctr Rare Earth & Inorgan Funct Mat,State Key Lab, Tianjin 300

CHEMICAL SCIENCE, 2019; 10 (16): 4394

Abstract

Through relatively subtle changes in reaction conditions, we have been able to isolate four distinct Rh/Sn cluster compounds, [Rh@Sn-10](3-), [Rh@Sn-1......

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