Aggregation of Polybismuthide Anions in a Single Compound Using Rh+-CO Units: Heterometallic Cluster Ions [Rh@Bi-10(RhCO)(6)](3-) and [Rh@Bi-9(RhCO)(5)](3-)

Chen, S; Li, ZY; Yuan, BB; Lin, LF; Whangbo, MH; Xu, L

Whangbo, MH; Xu, L (corresponding author), Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China.; Whangbo, MH (corresponding author), North Carolina Slate Univ, Dept Chem, Raleigh, NC 27695 USA.

INORGANIC CHEMISTRY, 2020; 59 (15): 10628

Abstract

In the presence of the roughly flat sequestering agent, [K(18-crown-6)](+), the reaction of Rh-2(CO)(4)Cl-2 with K5Bi4 in ethylenediamine (en) solutio......

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