Reductive Trapping of [(OC)(5)W-W(CO)(5)](2-) in a Mixed-Valent Sm-II/III Calix[4]pyrrolide Sandwich

Deacon, GB; Guo, ZF; Junk, PC; Wang, J

Deacon, GB (reprint author), Monash Univ, Sch Chem, Clayton, Vic 3800, Australia.; Junk, PC (reprint author), James Cook Univ, Coll Sci & Engn, Townsville, Qld 4811, Australia.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017; 56 (29): 8486

Abstract

Reduction of tungsten hexacarbonyl by the divalent samarium(II) complex [Sm-2(N4Et8)(thf)(4)] ((N4Et8)(4-) = meso-octaethylcalix[4]pyrrolide) in tolue......

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