The Dichotomy of Gold-catalyzed Interplay between Cyanamides and Ynamides: Controllable Switch from [2+2+2] to [4+2] Cycloaddition

Dubovtsev, AY; Shcherbakov, NV; Dar'in, DV; Kukushkin, VY

Dubovtsev, AY; Kukushkin, VY (corresponding author), St Petersburg State Univ, Inst Chem, Univ Skaya Nab 7-9, St Petersburg 199034, Russia.

ADVANCED SYNTHESIS & CATALYSIS, 2020; 362 (13): 2672

Abstract

The gold-catalyzed interplay between cyanamides and ynamides demonstrates condition-dependent mechanistic dichotomy. [2+2+2] Cycloaddition proceeds un......

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