Tricyanidoferrates(-IV) and Ruthenates(-IV) with Non-Innocent Cyanido Ligands

Jach, F; Wagner, FR; Amber, ZH; Rusing, M; Hunger, J; Prots, Y; Kaiser, M; Bobnar, M; Jesche, A; Eng, LM; Ruck, M; Hohn, P

Jach, F (corresponding author), Max Planck Inst Chem Phys Solids, Nothnitzer Str 40, D-01187 Dresden, Germany.; Jach, F (corresponding author), Tech Univ Dresden, Fac Chem & Food Chem, D-01062 Dresden, Germany.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021; 60 (29): 15879

Abstract

Exceptionally electron-rich, nearly trigonal-planar tricyanidometalate anions [Fe(CN)(3)](7-) and [Ru(CN)(3)](7-) were stabilized in LiSr3[Fe(CN)(3)] ......

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