Biosynthesis of Spinosyn A: A [4+2] or [6+4] Cycloaddition?

Chen, NH; Zhang, F; Wu, RB; Hess, BA

Wu, RB (reprint author), Sun Yat Sen Univ, Sch Pharmaceut Sci, Guangzhou 510006, Guangdong, Peoples R China.; Hess, BA (reprint author), Vanderbilt Univ, Dept Chem, Nashville, TN 37235 USA.

ACS CATALYSIS, 2018; 8 (3): 2353

Abstract

SpnF, one of the DielsAlderases, produces spinosyn A, and previous work demonstrated that its sole function is to catalyze the [4 + 2] cycloaddition (......

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