Mechanochemical C-H bond activation: Synthesis of the tuckover hydrides, (C5Me5)(2)Ln(mu-H)(mu-eta(1): eta(5)-CH2C5Me4)Ln(C5Me5) from solvent-free reactions of (C5Me5)(2)Ln(mu-Ph)(2)BPh2 with KC5Me5

Woen, DH; White, JRK; Ziller, JW; Evans, WJ

Evans, WJ (reprint author), Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2019; 899 ():

Abstract

Attempts to synthesize the sterically crowded complexes (C5Me5)(3)Ln of the smallest lanthanide metals, Ln = Tm and Lu, from (C5Me5)(2)Ln(mu-Ph)(2)BPh......

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