1-Aza-2,4-disilabicyclo[1.1.0]butanes with Superelongated C-N sigma-Bonds

Li, JC; Goffitzer, DJ; Xiang, MY; Chen, YL; Jiang, WJ; Diefenbach, M; Zhu, HP; Holthausen, MC; Roesky, HW

Holthausen, MC (corresponding author), Goethe Univ Frankfurt, Inst Anorgan & Analyt Chem, D-60438 Frankfurt, Germany.; Li, JC; Zhu, HP (corresponding author), Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China.; Roesky, HW (corresponding author), Georg August Univ, Inst Anorgan Chem, D-37077 Gottingen, Germany.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021; 143 (22): 8244

Abstract

Two silylene molecules oxidatively react under formal [1 + 2 + 1]-cycloaddition to the C N bond of nitriles to yield 1-aza-2,4-disilabicyclo[1.1.0]but......

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