Reactivity of hydride bridges in a high-spin [Fe-3(mu-H)(3)](3+) cluster: reversible H-2/CO exchange and Fe-H/B-F bond metathesis

Anderton, KJ; Knight, BJ; Rheingold, AL; Abboud, KA; Garcia-Serres, R; Murray, LJ

Murray, LJ (reprint author), Univ Florida, Ctr Catalysis, 214 Leigh Hall,POB 117200, Gainesville, FL 32611 USA.

CHEMICAL SCIENCE, 2017; 8 (5): 4123

Abstract

The triiron trihydride complex Fe3H3L (1) [where L3- is a tris(beta-diketiminate)cyclophanate] reacts with CO and with BF3 center dot OEt2 to afford (......

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