Structure and Methylene Transfer Reactivity of Thiolate-Bridged Dichromium Methylene Complexes Derived from Dihalomethane via Cleavage of Two Carbon-Halogen Bonds

Wei, NAM; Yang, DW; Zhao, JF; Mei, T; Zhang, YX; Wang, BM; Qu, JP

Yang, DW; Qu, JP (corresponding author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.; Qu, JP (corresponding author), East China Univ Sci & Technol, Frontiers Sci Ctr Materiobiol & Dynam Chem, Collaborat Innovat Ctr Biomfg, State Key Lab Bioreactor Engn, Shanghai 200237, Peoples R China.

ORGANOMETALLICS, 2021; 40 (10): 1434

Abstract

Using sterically demanding Cp' (Cp' = eta(5)-1,2,4-(Bu3C5H2)-Bu-t) as auxiliary ligands, coordinatively unsaturated thiolate-bridged (CrCrII)-Cr-II co......

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