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Influence of the 1,3-Bis(trimethylsilyl)cyclopentadienyl Ligand on the Reactivity of the Uranium Phosphinidene [eta(5)-1,3-(Me3Si)(2)C5H3](2)U(=P-2,4,6-(Pr3C6H2)-Pr-i)(OPPh3)

期刊: ORGANOMETALLICS, 2021; 40 (13)

At ambient temperature [eta(5)-1,3-(Me3Si)(2)C5H3](2)U(Cl) Me (3) reacts with 2,4,6-(Pr3C6H2PHK)-Pr-i in toluene in the presence of Ph3PO to yield the......

Terminal-Selective C(sp(3))-H Arylation: NiH-Catalyzed Remote Hydroarylation of Unactivated Internal Olefins

期刊: ORGANOMETALLICS, 2021; 40 (14)

A terminal-selective migratory hydroarylation of unactivated olefins has been developed though a NiH-catalyzed alkene isomerization-hydroarylation rel......

Nature of Heterobinuclear Ni(I) Complexes Formed upon the Activation of the alpha-Diimine Complex (LNiBr2)-Br-II with AlMe3 and MMAO

期刊: ORGANOMETALLICS, 2021; 40 (7)

The nature of Ni(I) species formed upon the activation of the N,N-alpha-diimine Ni(II) ethylene polymerization precatalyst (LNiBr2)-Br-II (1) with AlM......

Cobalt-Catalyzed (E)-Selective Hydrosilylation of 1,3-Enynes for the Synthesis of 1,3-Dienylsilanes

期刊: ORGANOMETALLICS, 2021; 40 (13)

Two types of regio- and stereoselective hydrosilylation reactions of 1,3-enynes catalyzed by Co complexes were developed. Dppf-CoCl2 is applicable for......

Ni-Catalyzed Coupling of Butadiene, Aldimines, and Arylboronic Acids to Homoallylic Amines under Base-Free Conditions

期刊: ORGANOMETALLICS, 2021; 40 (14)

Herein, we report a nickel-catalyzed three-component coupling of butadiene, aldimines, and arylboronic acids to form synthetically important homoallyl......

Chromium-Catalyzed Borylative Coupling of Aliphatic Bromides with Pinacolborane by Hydrogen Evolution

期刊: ORGANOMETALLICS, 2021; 40 (14)

The chromium-catalyzed borylative coupling between aliphatic bromides and pinacolborane (HBpin) is described. This reaction was promoted by low-cost a......

Ru-Catalyzed Site-Selective Aliphatic C-H Bond Silylation of Amides and Carbamides

期刊: ORGANOMETALLICS, 2021; 40 (15)

Hydrido ruthenium complexes (POCNP)RuH-(NBD) (NBD = norbornadiene) supported by N/O-bridged pincer ligands have been synthesized and characterized. Th......

Mesoionic-Carbene-Stabilized Thiophosphoryl Cation (PS+)

期刊: ORGANOMETALLICS, 2021; 40 (9)

The mesoionic carbene-stabilized PS+ cation 6 has been synthesized and first characterized by single-crystal X-ray diffraction analysis. Computational......

Pd-Catalyst Containing a Hemilabile P,C-Hybrid Ligand in Amino Dicarbonylation of Aryl Halides for Synthesis of alpha-Ketoamides

期刊: ORGANOMETALLICS, 2021; 40 (8)

The amino dicarbonylation of aryl halides affording a-ketoamides with Pd catalysts is highly dependent on the stereoelectronic properties of the invol......

C(sp(2))-X (X = Cl, Br, and I) Reductive Eliminations from Well-Defined Gold(III) Complexes: Concerted or Dissociation Pathways?

期刊: ORGANOMETALLICS, 2021; 40 (14)

A series of halogenated organogold(III) complexes cis-[(L)Au(Ar-F)(Cl)(X)] (L = phosphine ligand, Ar-F = 2,2',3,3',5,5',6,6'-octafluoro-[1,1'-biphenyl......

A Cobalt-Catalyzed Enantioconvergent Radical Negishi C(sp(3)) - C(sp(2)) Cross-Coupling with Chiral Multidentate N,N,P-Ligand

期刊: ORGANOMETALLICS, 2021; 40 (14)

A cobalt-catalyzed enantioconvergent radical Negishi C(sp(3))-C(sp(2)) cross-coupling of racemic benzyl chlorides with arylzinc reagents has been deve......

C(sp(2))-CF3 Reductive Elimination from Well-Defined Argentate(III) Complexes [nBu(4)N][Ag(Ar)(CF3)(3)]

期刊: ORGANOMETALLICS, 2021; 40 (11)

The preparation of a series of well-defined, shelf-stable square planar aryl(tris(trifluoromethyWargentate(HI) complexes [nBu(4)N](+)[Ag(Ar)(CF3)(3)](......

Structure and Methylene Transfer Reactivity of Thiolate-Bridged Dichromium Methylene Complexes Derived from Dihalomethane via Cleavage of Two Carbon-Halogen Bonds

期刊: ORGANOMETALLICS, 2021; 40 (10)

Using sterically demanding Cp' (Cp' = eta(5)-1,2,4-(Bu3C5H2)-Bu-t) as auxiliary ligands, coordinatively unsaturated thiolate-bridged (CrCrII)-Cr-II co......

Ligand-Induced Product Switching between 4-Methyl-1-pentene and 2-Methyl-1-pentene in Bis(imino)pyridine/V(III)-Catalyzed Propylene Dimerization: Cossee-Arlman Versus Metallacycle Mechanism

期刊: ORGANOMETALLICS, 2021; 40 (11)

Ligand-induced product switching between 4-methyl-1-pentene (4M1P) and 2-methyl-1-pentene (2M1P) for propylene dimerization with a bis(imino)pyridine ......

Dual Photoredox-/Palladium-Catalyzed Cross-Electrophile Couplings of Polyfluoroarenes with Aryl Halides and Triflates

期刊: ORGANOMETALLICS, 2021; 40 (14)

A visible-light photoredox-/Pd-catalyzed cross-electrophile arylation of polyfluoroarenes with aryl halides and triflates in the presence of dialkylam......

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