C(sp(2))-X (X = Cl, Br, and I) Reductive Eliminations from Well-Defined Gold(III) Complexes: Concerted or Dissociation Pathways?

Kang, K; Liu, SA; Xu, CH; Lu, ZH; Liu, SS; Leng, XB; Lan, Y; Shen, QL

Shen, QL (corresponding author), Chinese Acad Sci, Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China.; Lan, Y (corresponding author), Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China.; Lan, Y (corresponding author), Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China.

ORGANOMETALLICS, 2021; 40 (14): 2231

Abstract

A series of halogenated organogold(III) complexes cis-[(L)Au(Ar-F)(Cl)(X)] (L = phosphine ligand, Ar-F = 2,2',3,3',5,5',6,6'-octafluoro-[1,1'-biphenyl......

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