Transition-Metal-Free Formation of C-E Bonds (E = C, N, O, S) and Formation of C-M Bonds (M = Mn, Mo) from N-Heterocyclic Carbene Mediated Fluoroalkene C-F Bond Activation-MedSci.cn

Transition-Metal-Free Formation of C-E Bonds (E = C, N, O, S) and Formation of C-M Bonds (M = Mn, Mo) from N-Heterocyclic Carbene Mediated Fluoroalkene C-F Bond Activation

Leclerc, MC; Gabidullin, BM; Da Gama, JG; Daifuku, SL; Iannuzzi, TE; Neidig, ML; Baker, RT

Baker, RT (reprint author), Univ Ottawa, Dept Chem & Biomol Sci, 30 Marie Curie, Ottawa, ON KIN 6NS, Canada.; Baker, RT (reprint author), Univ Ottawa, Ctr Catalysis Res & Innovat, 30 Marie Curie, Ottawa, ON KIN 6NS, Canada.

Abstract

Herein, a recently reported polyfluoroalkenyl imidazolium salt is shown to react with nitrogen-, oxygen- and sulfur-based nucleophiles at the C-beta p......

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Transition-Metal-Free Formation of C-E Bonds (E = C, N, O, S) and Formation of C-M Bonds (M = Mn, Mo) from N-Heterocyclic Carbene Mediated Fluoroalkene C-F Bond Activation

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