Tuning of alpha-Silyl Carbocation Reactivity into Enone Transposition: Application to the Synthesis of Peribysin D, E-Volkendousin, and E-Guggulsterone

Athawale, PR; Zade, VM; Krishna, GR; Reddy, DS

Reddy, DS (corresponding author), CSIR, Organ Chem Div, Natl Chem Lab, Pune 411008, Maharashtra, India.; Reddy, DS (corresponding author), Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India.; Reddy, DS (corresponding author), CSIR, Indian Inst Integrat Med, Jammu 180001, India.

ORGANIC LETTERS, 2021; 23 (17): 6642

Abstract

A reliable method for enone transposition has been developed with the help of silyl group masking. Enantio-switching, substituent shuffling, and Z-sel......

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