Influence of the 1,3-Bis(trimethylsilyl)cyclopentadienyl Ligand on the Reactivity of the Uranium Phosphinidene [eta(5)-1,3-(Me3Si)(2)C5H3](2)U(=P-2,4,6-(Pr3C6H2)-Pr-i)(OPPh3)

Wang, SC; Li, TY; Heng, Y; Hou, GH; Zi, GF; Walter, MD

Zi, GF (corresponding author), Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China.; Walter, MD (corresponding author), Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany.

ORGANOMETALLICS, 2021; 40 (13): 2149

Abstract

At ambient temperature [eta(5)-1,3-(Me3Si)(2)C5H3](2)U(Cl) Me (3) reacts with 2,4,6-(Pr3C6H2PHK)-Pr-i in toluene in the presence of Ph3PO to yield the......

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