E-Z Isomerization of Phosphine-Olefin (PEWO-F-4) Ligands Revealed upon PdCl2 Capture: Facts and Mechanism

Penas-Defrutos, MN; Velez, A; Gioria, E; Espinet, P

Espinet, P (reprint author), Univ Valladolid, Fac Ciencias, IU CINQUIMA Quim Inorgan, E-47071 Valladolid, Spain.

ORGANOMETALLICS, 2019; 38 (24): 4701

Abstract

The PEWO phosphines R2P(o-C6H4CH=CHC-(O)Ph), R2P(o-C6H2F2CH=CHC(O)Ph), and R2P(o-C6F4CH=CHC(O)Ph) and their P-monodentate complexes trans-[PdCl2(P-mon......

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